Tetrahedron Letters p. 6253 - 6256 (1998)
Update date:2022-09-26
Topics:
Oi, Shuichi
Kashiwagi, Kenji
Inoue, Yoshio
A cationic palladium(II) complex, [PdL2(RCN)2](BF4)2, has been found to catalyze the Diels-Alder reaction of α, β-unsaturated carbonyl compounds with dienes, affording the corresponding cycloadducts in good yields. Excellent enanlioselectivity can be achieved in the reaction of N- acryloyloxazolidinone and cyclopentadiene by use of a chiral ligand, BINAP.
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