Tetrahedron Letters p. 6417 - 6420 (1989)
Update date:2022-08-05
Topics:
Toshima, Kazunobu
Misawa, Mari
Ohta, Kazumi
Tatsuta, Kuniaki
Kinoshita, Mitsuhiro
A complex C20-C28 segment 5 of concanamycin A (1) has been first synthesized without side reactions by effective de-O-silylation of 2a, which was constructed from the ethyl ketone 3 by glycosidation with the fluoride 4.
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