Silylation of 1-Alkynes with Chlorosilanes Promoted by Zinc: Preparation of Alkynylsilanes in a Single Step

DOI: 10.1016/0040-4039(95)00391-O

Source and publish data:

Tetrahedron Letters p. 2769 - 2772 (1995)

Update date:2022-08-05

Topics:

Authors:

Sugita, Hikaru

Hatanaka, Yasuo

Hiyama, Tamejiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)00391-O

The direct silylation of 1-alkynes with chlorosilanes smoothly takes place in the presence of zinc powder in acetonitrile, giving good yields of alkynylsilanes.The reactions are tolerant of a wide range of functionalities such as carboxylic acid, ester, alcohol, and chlorine in the 1-alkynes.

Full text of DOI:10.1016/0040-4039(95)00391-O

Products guided by the article

Product name:5-trimethylsilyl-pent-5-yn-1-oic acid

Cas No:128545-15-3

R&D Labs maybe for 128545-15-3

jintan yufan Medicine Raw materials Co.,Ltd.(expird)

Contact:86-519-82808282

Address:6th,Jincheng Huangzhuang
Hangzhou Neway Chemicals Co., Ltd.

Contact:+86-571-85095566

Address:Room 803, Qinglian Bldg, No 139 Qingchun Road, Hangzhou, Zhejiang China
Taizhou Chenyi chemical co. LTD,

Contact:13736652831

Address:NO.273 SHANGHAI SOUTH STREET,LUQIAO DISTRICT,ZHEJIANG PROVINCE,CHINA.
Nanjing HuiBaiShi Biotechnology Co.,Ltd.

Contact:+86 (25)58745219

Address:No.606 Ningliu Road,LiuHe District.
Shanghai Mokai Pharmaceutical Co.,Ltd

Contact:021-60257269

Address:Rm506,No.915,Zhenbei Road,Shanghai,200333,China

Relevant to this article

Biosynthesis of 2-Methylbutyl, 2-Methyl-2-butenyl, and 2-Methylbutanoate Esters in Red Delicious and Granny Smith Apples Using Deuterium-Labeled Substrates

Doi:10.1021/jf9508209
(1996)
Improved O/S exchange reagents

Doi:10.1055/s-1984-30980
(1984)
Synthesis of labelled [¹³C₆]testosterone and [¹³C₅]19-nortestosterone

Doi:10.1002/jlcr.2580360806
(1995)
Peptidomimetic inhibitors of farnesyltransferase with high in vitro activity and significant cellular potency

Doi:10.1016/j.bmcl.2007.09.015
(2007)
Microporous materials derived from two- and three-dimensional hyperbranched conjugated polymers by thermal elimination of substituents

Doi:10.1039/b707925g
(2007)
A NEW SYNTHESIS OF 5-METHYLENE-2(5H)-FURANONE DERIVATIVES

Doi:10.1016/S0040-4020(01)88810-4
(1984)

Article Doi