Tetrahedron Letters p. 2769 - 2772 (1995)
Update date:2022-08-05
Topics:
Sugita, Hikaru
Hatanaka, Yasuo
Hiyama, Tamejiro
The direct silylation of 1-alkynes with chlorosilanes smoothly takes place in the presence of zinc powder in acetonitrile, giving good yields of alkynylsilanes.The reactions are tolerant of a wide range of functionalities such as carboxylic acid, ester, alcohol, and chlorine in the 1-alkynes.
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