Silylation of 1-Alkynes with Chlorosilanes Promoted by Zinc: Preparation of Alkynylsilanes in a Single Step

DOI: 10.1016/0040-4039(95)00391-O

Source and publish data:

Tetrahedron Letters p. 2769 - 2772 (1995)

Update date:2022-08-05

Topics:

Authors:

Sugita, Hikaru

Hatanaka, Yasuo

Hiyama, Tamejiro

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Article abstract of DOI:10.1016/0040-4039(95)00391-O

The direct silylation of 1-alkynes with chlorosilanes smoothly takes place in the presence of zinc powder in acetonitrile, giving good yields of alkynylsilanes.The reactions are tolerant of a wide range of functionalities such as carboxylic acid, ester, alcohol, and chlorine in the 1-alkynes.

Full text of DOI:10.1016/0040-4039(95)00391-O

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