Excellent stereocontrol in intramolecular Buchner cyclisations and subsequent cycloadditions; stereospecific construction of polycyclic systems

DOI: 10.1039/cc9960002595

Source and publish data:

Chemical Communications p. 2595 - 2596 (1996)

Update date:2022-08-04

Topics:

Authors:

Maguire, Anita R.

Buckley, N. Rachael

O'Leary, Patrick

Ferguson, George

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Article abstract of DOI:10.1039/cc9960002595

Highly diastereoselective rhodium(II) acetate-catalysed intramolecular addition of α-diazo ketones to aromatic rings to form the azulenones 3 has been achieved; the norcaradiene form of 3 undergoes efficient stereospecific cycloaddition with phenyltriazol

Full text of DOI:10.1039/cc9960002595

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