An unexpected formation of a new 3-imidazoline free radical

DOI: 10.1016/S0040-4020(01)89778-7

Source and publish data:

Tetrahedron p. 2129 - 2134 (1990)

Update date:2022-08-06

Topics:

Authors:

Rijk Rijk

Tesser Tesser

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Article abstract of DOI:10.1016/S0040-4020(01)89778-7

A new 3-imidazoline has been formed unexpectedly in the reaction between 2,4-dibromo- 2,4-dimethylpentanone-3 and concentrated aqueous ammonia. A crystalline nitroxide formed upon oxidation with hydrogen peroxide. Its identity has been proved by X-ray analysis. A feasible mechanism for the present reaction is given.

Full text of DOI:10.1016/S0040-4020(01)89778-7

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