Tetrahedron p. 2129 - 2134 (1990)
Update date:2022-08-06
Topics:
Rijk
Tesser
A new 3-imidazoline has been formed unexpectedly in the reaction between 2,4-dibromo- 2,4-dimethylpentanone-3 and concentrated aqueous ammonia. A crystalline nitroxide formed upon oxidation with hydrogen peroxide. Its identity has been proved by X-ray analysis. A feasible mechanism for the present reaction is given.
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Doi:10.1002/ejic.201001195
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