Carbohydrate Research p. 49 - 56 (1993)
Update date:2022-08-03
Topics:
Maeta
Matsumoto
Suzuki
The Bu2SnCl2-2AgClO4 combination shows promise as an activator for glycosyl fluorides, as revealed by experiments with 2,3,4,6-tetra-O-benzyl-α-D-mannosyl fluoride as a model glycosyl donor in comparison with activators prepared in situ from five types of organotin chlorides (Bu2SnCl2, Me2SnCl2, Bu3SnCl, Me3SnCl, and Ph3SnCl) in combination with silver perchlorate. The Bu2SnCl2-2AgClO4 combination shows promise as an activator for glycosyl fluorides, as revealed by experiments with 2, 3,4,6-tetra-O-benzyl-α-D-mannosyl fluoride as a model glycosyl donor in comparison with activators prepared in situ from five types of organotin chlorides (Bu2SnCl2, Me2SnCl2, Bu3 SnCl, Me3SnCl, and Ph3SnCl) in combination with silver perchlorate.
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