An expeditious enantioselective synthesis of γ-lactones

DOI: 10.1016/S0040-4039(00)88894-2

Source and publish data:

Tetrahedron Letters p. 1981 - 1984 (1990)

Update date:2022-08-05

Topics:

Authors:

Chong Chong

Mar Mar

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Article abstract of DOI:10.1016/S0040-4039(00)88894-2

α-Alkoxyorganolithium reagents react with α,β-unsaturated trimethylhydrazides to give γ-alkoxytrimethylhydrazides in moderate to good yields. Acid hydrolysis of the latter compounds yields γ-lactones. A short enantioselective route to (S)-hexanolide is described.

Full text of DOI:10.1016/S0040-4039(00)88894-2

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