C-H insertion method for the chiral tertiary alcohol: Formal synthesis of (-)-frontalin

DOI: 10.1016/S0040-4039(00)94424-1

Source and publish data:

Tetrahedron Letters p. 1039 - 1040 (1990)

Update date:2022-07-31

Topics:

Authors:

Ohira, Susumu

Ishi, Satoshi

Shinohara, Koji

Nozaki, Hiroshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)94424-1

Intramolecular insertion of the alkylidene carbene into C - H bond adjacent to the protected secondary hydroxyl group gave a chiral tertiary alcohol derivative, which was converted to a synthetic intermediate of (-)-frontalin.

Full text of DOI:10.1016/S0040-4039(00)94424-1

Products guided by the article

Product name:Toluene-4-sulfonic acid (S)-2,2-dimethyl-4-(3-oxo-butyl)-[1,3]dioxolan-4-ylmethyl ester

Cas No:128766-40-5

R&D Labs maybe for 128766-40-5

Tianjin Dongchang Fine Chemical Industry Co., Ltd.

Contact:+86-22-29894595

Address:Economic Developing Zone, Ji County, Tianjin, China
Weinan Rigel Pharm Co., Ltd.

Contact:+86-913-2223392

Address:No. 32, Xinanjing Road, Weinan City, Shaanxi Province, 714000, China
Anhui Jiatiansen Agrochemical Co.,Ltd

Contact:15366811918

Address:chemical industrial park,xiangyu town,dongzhi county,anhui,china
Zouping Mingxing Chemical Co.,Ltd.

website:http://www.zoutong.com.cn

Contact:86-543-2240068 2240067

Address:428 Daixi Third Road Zouping County Shandong Province China
ZHEJIANG JIANYE CHEMICAL CO.,LTD.

Contact:86-571-64149273,64149234

Address:No. 48, Fuxi Road, Meicheng Town

Relevant to this article

Synthesis of spiro-pyridones and spiro-quinolones by sequential palladium on carbon-catalyzed allylation and ring closing metathesis reactions

Doi:10.1016/j.tetlet.2008.11.026
(2009)
Gold-Catalyzed Synthesis of Tropone and Its Analogues via Oxidative Ring Expansion of Alkynyl Quinols

Doi:10.1021/acs.orglett.5b03160
(2015)
Synthesis, experimental and theoretical NMR study of 2′- hydroxychalcones bearing a nitro substituent on their B ring

Doi:10.1016/j.tet.2004.06.005
(2004)
Palladium-Catalyzed Intramolecular C?H Arylation versus 1,5-Palladium Migration: A Theoretical Investigation

Doi:10.1002/asia.201800603
(2018)
β-Acetyl-β-nitrostyrenes: Structure and use for synthesis of heteryl-containing structures

Doi:10.1134/S1070363208090120
(2008)
Doi:10.1016/S0040-4020(01)82117-7
(1966)

Article Doi