C-H insertion method for the chiral tertiary alcohol: Formal synthesis of (-)-frontalin

DOI: 10.1016/S0040-4039(00)94424-1

Source and publish data:

Tetrahedron Letters p. 1039 - 1040 (1990)

Update date:2022-07-31

Topics:

Authors:

Ohira, Susumu

Ishi, Satoshi

Shinohara, Koji

Nozaki, Hiroshi

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Article abstract of DOI:10.1016/S0040-4039(00)94424-1

Intramolecular insertion of the alkylidene carbene into C - H bond adjacent to the protected secondary hydroxyl group gave a chiral tertiary alcohol derivative, which was converted to a synthetic intermediate of (-)-frontalin.

Full text of DOI:10.1016/S0040-4039(00)94424-1

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