Methylenecyclopentane Annulations of Unactivated and Electron-Rich Olefins with 2-(Phenylsulfonyl)-1-methylenecyclopropanes

DOI: 10.1021/jo00303a002

Source and publish data:

Journal of Organic Chemistry p. 4780 - 4782 (1990)

Update date:2022-08-05

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Authors:

Singleton, Daniel A.

Church, Kevin M.

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Article abstract of DOI:10.1021/jo00303a002

The thiyl radical catalyzed reaction of 1 with unactivated and electron-rich olefins affords methylenecyclopentanes regiospecifically.Using irradiation in the presence of dibutyl disulfide, these reactions can be achieved using equimolar amounts of olefin

Full text of DOI:10.1021/jo00303a002

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