Tetrahedron Letters p. 1799 - 1802 (1990)
Update date:2022-09-26
Topics:
Avery, Mitchell A.
Chong, Wesley K. M.
Detre, George
An efficient synthesis of (+)-8a,9-secoartemisinin 2, a ring-D cleaved, tricyclic analog of (+)-artemisinin 1, has been accomplished.Dioxetane 7, produced upon ozonolysis of vinyl-silane 5 in methanol, was intercepted with acid to provide the stable bicylic peroxy-aldehyde 9, which was readily converted to the title compound(s).
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Doi:10.1016/0040-4039(90)80155-F
(1990)Doi:10.1039/c9cc03509e
(2019)Doi:10.1016/j.ejmech.2011.01.066
(2011)Doi:10.1021/ml200018n
(2011)Doi:10.1248/cpb.38.312
(1990)Doi:10.1021/jo00312a034
(1990)
