Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 967 - 974 (1990)
Update date:2022-09-26
Topics:
Dzhemilev, U. M.
Gaisin, R. L.
Turchin, A. A.
Khalikova, N. R.
Baikova, I. P.
Tolstikov, G. A.
We have investigated the reductive dehalogenation reaction of alkyl and aryl substituted gem-dihalocyclopropanes with diisobutyl aluminum hydride in the presence of catalytic amounts of titanium and zirconium complexes.As a result we propose a general method for the synthesis of substituted monohalocyclopropanes and cyclopropanes of various structures.We have also studied the stereochemistry of the reduction.
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Doi:10.1039/c0nj00732c
(2011)Doi:10.1002/jhet.5570270362
(1990)Doi:10.1016/0008-6215(90)84084-8
(1990)Doi:10.1016/0031-9422(90)83005-L
(1990)Doi:10.1021/jo00305a014
(1990)Doi:10.1002/hc.20670
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