Tetrahedron Letters p. 2127 - 2130 (1990)
Update date:2022-08-03
Topics:
Saluzzo, Christine
Alvernhe, Gerard
Anker, Daniel
Haufe, Guenter
The electrophilic anti-addition of the elements of benzeneselenenyl fluoride towards carbone-carbone triple bonds is performed by a one-pot reaction of N-phenylselenophthalimide and triethylamine tris-hydrofluoride with disubstituted alkynes ; starting from monosubstituted alkynes, the reaction proceeds further to afford vinylic diselenated compounds after hydrofluoric acid elimination. Some products of mono-addition could be transformed into vinylic or allenic fluorides.
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(1990)Doi:10.1055/s-1981-29479
(1981)Doi:10.1021/jo00309a013
(1990)Doi:10.1248/cpb.25.520
(1977)Doi:10.1016/S0040-4039(01)80330-0
(1989)Doi:10.1007/s11172-015-1148-3
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