The Stereochemistry of the Sulfur Atom of 4,7-Dimethyl-6-phenyl-5,6,7,8-tetraahydro-4H-1,3,2,6-dioxathiazocine 2-Oxides

Article abstract of DOI:10.1246/bcsj.65.2294

The reaction of N-(2-hydroxypropyl)-N-(2-hydroxy-1-methylethyl)aniline with thionyl chloride afforded four isomers of 4,7-dimethyl-6-phenyl-5,6,7,8-tetrahydro-4H-1,3,2,6-dioxathiazocine 2-oxide.Oxidation of the four isomers by the use of KMnO4 yielded two