Tetrahedron p. 3819 - 3822 (1990)
Update date:2022-07-29
Topics:
Teshima, Tadashi
Matsumoto, Takahiro
Miyagawa, Masaaki
Wakamiya, Tateaki
Shiba, Tetsuo
Narai, Noriko
Yoshioka, Masanori
Clavamine, a new insecticidal toxin isolated from the venom of Joro spider (Nephila clavata) was totally synthesized in order to confirm the proposed structure. In clavamine, a fragment of glycylalanine is inserted in the structure of NSTX-3, a New Guinean spider toxin. The synthesis determined the chemical structure of clavamine unambiguously.
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Doi:10.1021/jo961818z
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(2017)
