PHYLLANTHOSIDE-PHYLLANTHOSTATIN SYNTHETIC STUDIES. 6. AN AUGMENTED SPIROKETALIZATION TACTIC FOR THE TOTAL SYNTHESIS OF PHYLLANTHOCIN

DOI: 10.1016/S0040-4039(00)70688-5

Source and publish data:

Tetrahedron Letters p. 7325 - 7328 (1989)

Update date:2022-07-29

Topics:

Authors:

Smith, Amos B.III

Empfield, James R.

Vaccaro, Henry A.

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Article abstract of DOI:10.1016/S0040-4039(00)70688-5

An enhanced spiroketalization maneuver permitting equilibration at both the C(8) and C(11) centers of spiroketals 17a,b leads to a more concise and efficient synthesis of phyllanthocin (i.e., 21 steps, 5.6percent overall yield).

Full text of DOI:10.1016/S0040-4039(00)70688-5

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