New Low-valent Titanium Reagents for Dicarbonyl Coupling and their Use in a General Method of Annulation

DOI: 10.1039/c39900000509

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 509 - 511 (1990)

Update date:2022-08-02

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Authors:

Clive, Derrick L. J.

Murthy, K. S. Keshava

Zhang, Chengzhi

Hayward, William D.

Daigneault, Sylvain

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Article abstract of DOI:10.1039/c39900000509

Ketones carrying a chain that incorporates a suitably placed oxo function (aldehyde or ketone) undergo intramolecular dicarbonyl coupling when treated with a reagent prepared either from titanium trichloride and C8K (relative molar ratio 1:2) or from tita

Full text of DOI:10.1039/c39900000509

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