Titanocene-catalyzed double silylation of dienes and aryl alkenes with chlorosilanes

DOI: 10.1016/S0040-4039(98)02227-8

Source and publish data:

Tetrahedron Letters p. 9697 - 9698 (1998)

Update date:2022-08-04

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Authors:

Terao, Jun

Kambe, Nobuaki

Sonoda, Noboru

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Article abstract of DOI:10.1016/S0040-4039(98)02227-8

Double silylation of 1,3-butadienes with chlorosilanes was found to proceed by using titanocene dichloride as the catalyst in the presence of (n)BuMgCl, giving rise to 1,4-disilylated 2-butenes in good yields. Aryl substituted alkenes also afforded 1,2-di

Full text of DOI:10.1016/S0040-4039(98)02227-8

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