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REDOX REACTIONS OF 3,6-DI-TERT-BUTYL-ORTHO-BENZOQUINONE, CATALYZED BY TETRAFLUOROSILANE

DOI: 10.1007/BF00961698

Source and publish data:

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 991 - 993 (1990)

Update date:2022-08-04

Topics:

Authors:

Chekalov, A. K.Chekalov, A. K.

Gvazava, N. G.Gvazava, N. G.

Vol'eva, V. B.Vol'eva, V. B.

Prokof'eva, T. I.Prokof'eva, T. I.

Prokof'ev, A. I.Prokof'ev, A. I.

Ershov, V. V.Ershov, V. V.

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Article abstract of DOI:10.1007/BF00961698

Tetrafluorosilane-catalyzed redox reactions of 3,6-di-tert-butyl-ortho-benzoquinone have been examined.From the EPR spectroscopic data and a study of the reaction products, a mechanism for these reactions is proposed involving the formation of a quinone-tetrafluorosilane complex which has strong oxidizing properties, and which enables the original quinone to undergo further reactions.

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Full text of DOI:10.1007/BF00961698

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