Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 991 - 993 (1990)
Update date:2022-08-04
Topics:
Chekalov, A. K.
Gvazava, N. G.
Vol'eva, V. B.
Prokof'eva, T. I.
Prokof'ev, A. I.
Ershov, V. V.
Tetrafluorosilane-catalyzed redox reactions of 3,6-di-tert-butyl-ortho-benzoquinone have been examined.From the EPR spectroscopic data and a study of the reaction products, a mechanism for these reactions is proposed involving the formation of a quinone-tetrafluorosilane complex which has strong oxidizing properties, and which enables the original quinone to undergo further reactions.
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Doi:10.1039/c5ra12099c
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