INTRAMOLECULAR REACTIONS OF ALLYLOXY RADICALS

DOI: 10.1016/S0040-4020(01)85798-7

Source and publish data:

Tetrahedron p. 7835 - 7858 (1989)

Update date:2022-08-04

Topics:

Authors:

Johns, Amanda

Murphy, John A.

Sherburn, Michael S.

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Article abstract of DOI:10.1016/S0040-4020(01)85798-7

Allyloxy radicals formed by epoxide cleavage, have cyclised onto appropriately positioned alkenes to form tetrahydrofurans, and the diastereoselectivity of the cyclisation has been studied.The reaction was used to synthesise lilac alcohols which were then used to confirm the stereochemistry of such cyclisations.

Full text of DOI:10.1016/S0040-4020(01)85798-7

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