Journal of Organic Chemistry p. 5344 - 5347 (1990)
Update date:2022-08-05
Topics:
Usypchuk, Laurie
Leblanc, Yves
A variety of 2-quinolinylmethyl ethers were efficiently cleaved by CuCl2 in DMF/H2O to regenerate the corresponding alcohols.The same cleavage also takes place with the 4-regioisomer.On the other hand, the 2- and 4-pyridinylmethyl analogues were found to be stable under these reaction conditions.A mechanistic scheme for this cleavage is proposed.
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Doi:10.1002/1097-458X(200006)38:6<468::AID-MRC675>3.0.CO;2-F
(2000)Doi:10.1021/ja110624k
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