Dehydrogenative silation, isomerization and the control of syn- vs. anti-addition in the hydrosilation of alkynes

DOI: 10.1016/0022-328X(93)80236-5

Source and publish data:

Journal of Organometallic Chemistry p. 177 - 187 (1993)

Update date:2022-08-05

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Authors:

Jun, Chul-Ho

Crabtree, Robert H.

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Article abstract of DOI:10.1016/0022-328X(93)80236-5

Alkyne hydrosilation has been examined in detail for the catalysts SbF6 (L = PPh3, bq = 7,8-benzoquinolinato) and RhCl(PPh3)3.Factors that favor the normal syn- or the unusual anti-silane addition to the alkynes are examined.Two other unus

Full text of DOI:10.1016/0022-328X(93)80236-5

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