Dehydrogenative silation, isomerization and the control of syn- vs. anti-addition in the hydrosilation of alkynes

DOI: 10.1016/0022-328X(93)80236-5

Source and publish data:

Journal of Organometallic Chemistry p. 177 - 187 (1993)

Update date:2022-08-05

Topics:

Authors:

Jun, Chul-Ho

Crabtree, Robert H.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(93)80236-5

Alkyne hydrosilation has been examined in detail for the catalysts SbF6 (L = PPh3, bq = 7,8-benzoquinolinato) and RhCl(PPh3)3.Factors that favor the normal syn- or the unusual anti-silane addition to the alkynes are examined.Two other unus

Full text of DOI:10.1016/0022-328X(93)80236-5

Products guided by the article

Product name:1-(methyldiphenylsilyl)-2-phenylethyne

Cas No:129762-91-0

R&D Labs maybe for 129762-91-0

Shanghai AoBo Bio-Pharmaceutical Technology Co., Ltd.

Contact:+86-21-51320130-801, 816

Address:Room 601, No. 1011, Halei Road, Zhangjiang High-Tech Park, Pudong, Shanghai
Shanghai Bojing Chemical Co., Ltd.

Contact:021-37122233

Address:6F Buildiing 11,No.388,Baifu Road,District Fengxian.Shanghai, China.
Tractus Company Limited

Contact:+852-8198 2399

Address:9E, Leapont Industrial Building, 18-28 Wo Liu Hang Road, Shatin, New Territories, Hong Kong
Yuan Shi(SuQian)Biotechnology Co.,Ltd

website:http://www.yuanshibio.com

Contact:+86-527-84226672

Address:jiangsu suqian
Shenyang NovPharm Technology Co., Ltd.

Contact:.+86-24-24165786

Address:Room 306, Hongjin Mansion, No. 36-1, Wanliutang Rd., Shenhe District, Shenyang, Liaoning, P.R.C.

Relevant to this article

Antiterminator-mediated unveiling of cryptic polythioamides in an anaerobic bacterium

Doi:10.1002/anie.201108214
(2012)
STRUCTURAL ELUCIDATION OF SPOROGENIC FATTY ACID METABOLITES FROM ASPERGILLUS NIDULANS

Doi:10.1016/S0040-4039(00)97482-3
(1990)
The Synthesis and Biophysical Investigations of Novel Ring-Expanded Nucleosides, Nucleotides, and Homopolymers Containing the 5:7-Fused Heterocyclic Ring System Imidazo<4,5-e><1,4>diazepine

Doi:10.1021/jo00310a021
(1990)
Monoamine oxidase (MAO-N) catalyzed deracemization of tetrahydro-β- carbolines: Substrate dependent switch in enantioselectivity

Doi:10.1021/cs400724g
(2013)
An efficient methodology to substituted furans via oxidation of functionalized α-diazo-β-ketoacetates

Doi:10.1016/j.tetlet.2010.11.166
(2011)
Doi:10.1021/jo00871a021
(1976)

Article Doi