STEREOSELECTIVE CYCLIZATION OF (E)- AND (Z)-5,6-DIMETHYL-8-TRIMETHYLSILYL-6-OCTENALS

DOI: 10.1016/S0040-4039(01)93905-X

Source and publish data:

Tetrahedron Letters p. 6397 - 6400 (1989)

Update date:2022-08-04

Topics: Regioselectivity Diastereoselectivity Column chromatography NMR spectroscopy Protecting group Intramolecular Reaction Nucleophilic Attack Chiral Auxiliary Tandem Reaction Lewis Acid Catalysis Ring Strain Conformational Control Stereoelectronic Effects Aldehyde Functional Group Oxocarbenium ion Trimethylsilyl (TMS) group

Authors:

Asao, Kazuhiko

Iio, Hideo

Tokoroyama, Takashi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)93905-X

The diastereoselectivities in the acid-mediated cyclization of (E)- and (Z)-5,6-dimethyl-8-trimethylsilyl-6-octenals, both stereoselectively synthesized, were investigated.Excellent preference for the formation of cis-dimethylcyclohexanols was realized, s

Full text of DOI:10.1016/S0040-4039(01)93905-X

Products guided by the article

Product name:(+/-)-2-allyl-2,3-dimethylcyclohexanone

Cas No:129523-91-7

R&D Labs maybe for 129523-91-7

shanghai payne pharm co.,ltd.

Contact:+86-021-58123769

Address:No.780 of Cailun Road,Zhangjiang Hi-tech Park,Pudong,Shanghai
Jiangsu King Road New Materials Co., Ltd.

website:http://www.jskingroad.com

Contact:0519-85720726 0519-85720721 13584535752

Address:No.1,Weihua Road,Xinbei District,Changzhou City,Jiangsu Province
WUHU HUAHAI BIOLOGY ENGINEERING CO LTD

Contact:+86-553-3836920

Address:7/F NO.82 LAODONG ROAD WUHU CHINA
Zhejiang Newfine Industry Co.,Ltd.

Contact:+86-573-82262042

Address:No.225,Dongqing Road, garoms@163.com
Chongqing Shuangfeng Chemical Co.,Ltd

Contact:+86-23-49850156

Address:No.663,xuanhua Rd,yongchuan,chongqing,China

Relevant to this article

Aryl extensions of thienopyrimidinones as fibroblast growth factor receptor 1 kinase inhibitors

Doi:10.1016/j.tetlet.2010.12.081
(2011)
Doi:10.1039/c39770000414
(1977)
REACTION OF α,α,ω-TRICHLORO- AND α,α,α,ω-TETRACHLOROALKANES WITH ALKALI METAL ACYLATES IN APROTIC SOLVENTS

Doi:10.1007/BF01184532
(1990)
Synthesis of 2-(2-hydroxybenzyl)phthalazin-1(2H)-ones

Doi:10.1007/s10593-011-0683-6
(2011)
Fe₃O₄@SiO₂-imid-PMAⁿ magnetic porous nanosphere as recyclable catalyst for the green synthesis of quinoxaline derivatives at room temperature and study of their antifungal activities

Doi:10.1016/j.materresbull.2015.10.002
(2016)
Synthesis of optically active α-aminophosphine oxides and enantioselective membrane transport of acids with their participation

Doi:10.1134/S107036321104027X
(2011)

Article Doi