Tetrahedron Letters p. 6397 - 6400 (1989)
Update date:2022-08-04
Topics: Regioselectivity Diastereoselectivity Column chromatography NMR spectroscopy Protecting group Intramolecular Reaction Nucleophilic Attack Chiral Auxiliary Tandem Reaction Lewis Acid Catalysis Ring Strain Conformational Control Stereoelectronic Effects Aldehyde Functional Group Oxocarbenium ion Trimethylsilyl (TMS) group
Asao, Kazuhiko
Iio, Hideo
Tokoroyama, Takashi
The diastereoselectivities in the acid-mediated cyclization of (E)- and (Z)-5,6-dimethyl-8-trimethylsilyl-6-octenals, both stereoselectively synthesized, were investigated.Excellent preference for the formation of cis-dimethylcyclohexanols was realized, s
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