REACTION OF α,α,ω-TRICHLORO- AND α,α,α,ω-TETRACHLOROALKANES WITH ALKALI METAL ACYLATES IN APROTIC SOLVENTS

Article abstract of DOI:10.1007/BF01184532

Polychloroalkanes and -alkenes R(CH2)nCl (R=CHCl2CH2, CCl2=CH, n=1,3) in dipolar aprotic solvents - dimethylformamide (DMF), dimethylsulfoxide (DMSO), hexamethylphosphoramide (HMPA) - at 130-150 deg C react selectively at the CH2Cl group with salts of car