Formation of trans Ring-Fused Compounds by an Alkylation-Radical Cyclization Sequence

DOI: 10.1021/jo00076a057

Source and publish data:

Journal of Organic Chemistry p. 6857 - 6873 (1993)

Update date:2022-08-04

Topics:

Authors:

Clive, Derrick L. J.

Manning, Hartford W.

Boivin, Taryn L. B.

Postema, Maarten H. D.

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Article abstract of DOI:10.1021/jo00076a057

Enolates derived from bicyclic lactones of type 1 (Scheme I) can be alkylated with 2-propynylic halides to give products 2, in which the unsaturated alkyl group is syn to the adjacent ring-fusion hydrogen.Reaction of 2 with sodium phenyl selenide and then

Full text of DOI:10.1021/jo00076a057

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