Stereocontrolled synthesis of lankanolide from 1,6-anhydro-beta-D-glucopyranose (levoglucosan): 1, synthesis of the C-1/7 and C-8/15 segments.

DOI: 10.1016/0008-6215(90)84192-W

Source and publish data:

Carbohydrate research p. 209 - 225 (1990)

Update date:2022-08-03

Topics:

Authors:

Kochetkov

Yashunsky

Sviridov

Ermolenko

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Article abstract of DOI:10.1016/0008-6215(90)84192-W

A scheme has been designed for the stereocontrolled synthesis of lankanolide, the aglycon of lankamycin. Synthesis of its C-1/7 and C-8/15 segments has been accomplished starting from 1,6-anhydro-2,4-dideoxy-2,4-di-C-methyl-beta-D-glucopyranose.

Full text of DOI:10.1016/0008-6215(90)84192-W

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Product name:2,4-dideoxy-5,6-O-isopropylidene-3-O-(p-methoxybenzyl)-2,4-di-C-methyl-D-glucose trimethylene dithioacetal

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