A Novel Intramolecular Cyclisation of Titanocene Vinylidene Complexes: Formation of Bicyclic Titanacyclo-butanes and -butenes

DOI: 10.1039/c39900001060

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1060 - 1062 (1990)

Update date:2022-08-02

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Authors:

Dennehy, Robert D.

Whitby, Richard J.

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Article abstract of DOI:10.1039/c39900001060

The intramolecular addition of a titanocene vinylidene complex formed by dechlorodimethylalumination of a 1-dimethylalumino-1-bis(η⁵-cyclopentadienyl)chlorotitano-alkene to an unactivated alkene or alkyne affords bicyclic titanacyclobutanes or titanacyclobutenes.

Full text of DOI:10.1039/c39900001060

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