Investigation of the Stereospecificity of Clavaminic Acid Synthase in the Desaturation of Dihydroclavaminic Acid to Clavaminic Acid

DOI: 10.1039/c39940001133

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1133 - 1134 (1994)

Update date:2022-08-05

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Authors:

Baldwin, Jack E.

Adlington, Robert M.

Crouch, Nicholas P.

Drake, David J.

Fujishima, Yoshiyuki

et al. et al.

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Article abstract of DOI:10.1039/c39940001133

Incubations of (4R)- and (4S)-<4-2H1>-proclavaminic acid with clavaminic acid synthase resulted in the stereospecific removal of the deuterium and hydrogen respectively from C-4, in their conversions to clavaminic acid, suggesting an enzyme catalysed syn-

Full text of DOI:10.1039/c39940001133

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