NOVEL METHOD FOR α-SUBSTITUTION OF AMINES VIA N-METHOXYCARBONYL-α-t-BUTYLDIOXYAMINES

DOI: 10.1016/S0040-4039(00)88520-2

Source and publish data:

Tetrahedron Letters p. 7475 - 7478 (1990)

Update date:2022-08-05

Topics:

Authors:

Naota, Takeshi

Nakato, Takeshi

Murahashi, Shun-Ichi

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Article abstract of DOI:10.1016/S0040-4039(00)88520-2

α-Substitution of amines can be performed by ruthenium-catalyzed oxidation of N-methoxycarbonylamines with t-butyl hydroperoxide followed by treatment with nucleophiles in the presence of titanium tetrachloride.

Full text of DOI:10.1016/S0040-4039(00)88520-2

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