Novel Preparation of Vinylphosphonates, Vinylphosphinates, and Vinylphosphine Oxides via β-Elimination of Nitrous Acid

DOI: 10.1055/s-1990-26893

Source and publish data:

Synthesis p. 420 - 422 (1990)

Update date:2022-07-30

Topics:

Authors:

Yamashita, Mitsuji

Tamada, Yoshinori

Iida, Akihito

Oshikawa, Tatsuo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1990-26893

Base treatment of 2-dimethoxyphosphinyl-, 2-methoxyphenylphosphinyl- and 2-diphenylphosphinyl-1-nitroethane derivatives results in β-elimination of nitrous acid to afford the corresponding vinyl derivatives in excellent yield.This is a useful method for t

Full text of DOI:10.1055/s-1990-26893

Products guided by the article

Product name:(3aR,5S,6R,6aR)-5-[1-(Diphenyl-phosphinoyl)-vinyl]-6-methoxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole

Cas No:130222-71-8

R&D Labs maybe for 130222-71-8

TIANJIN NORTH JINHENG CHEMICAL PLANT.

Contact:0086-22-59952083

Address:DongShigu Country In JiXian TianJin China
Nanjing lanbai chemical Co.,Ltd.

Contact:+86-25-85499326

Address:Room 908, 9F Taiyue Building,No.285 Heyan Road
SJZ Chenghui Chemical Co., Ltd.

Contact:86-311-87713916

Address:no.368 youyi north avenue
Jinan Kaypharm Chemical Co.,Ltd

Contact:86-0531-86986780

Address:Room101,No189-2,Huayuan Road,Jinan City,Shandong Province
Jiangxi Province Bethel Pharmaceutical Co., Ltd.

Contact:+86-795-259 3456 ，+86-15957688008 13566650571

Address:Huangjindui Chemical Park， Shanggao County ，Yichun city，Jiangxi Province

Relevant to this article

SYNTHETIC STUDIES ON ASPIROCHLORINE (A30641)

Doi:10.1016/S0040-4039(00)97605-6
(1990)
Efficient, one-pot synthesis of polyfunctionalised octahydroquinazolin-2,5-diones catalysed by Fe₃O₄ nanoparticles

Doi:10.3184/174751915X14199511243271
(2015)
Trifluoroethanol and liquid-assisted grinding method: a green catalytic access for multicomponent synthesis

Doi:10.1007/s11164-017-3206-y
(2018)
Sulfoxide-mediated α-arylation of carbonyl compounds

Doi:10.1021/ja2031882
(2011)
Pyrrolo[3,2-e][1,4]diazepin-2-one synthesis: A head-to-head comparison of soluble versus insoluble supports

Doi:10.1021/jo200424q
(2011)
Preparation of half-titanocenes of thiophene-fused trimethylcyclopentadienyl ligands and their ethylene copolymerization reactivity

Doi:10.1016/j.jorganchem.2011.03.014
(2011)

Article Doi