Journal of Organic Chemistry p. 5446 - 5448 (1990)
Update date:2022-07-29
Topics: Functionalized Preparation Olefination Alkylidenemalonates
Tucker, Charles E.
Rao, S. Achyutha
Knochel, Paul
The polyfunctional alkylidenemalonates 1, readily prepared by an addition-elimination reaction of FG-RCu(CN)ZnI to <(phenylsulfonyl)methylidene>malonates of type 7, were found to undergo a highly chemoselective and stereoselective olefination reaction with 1,1-dimetalloalkanes of zinc and magnesium.An application to the stereospecific preparation of an insect pheromone 8 is reported.
View MoreNanjing Samwon International Limited
Contact:+86-25-84873444
Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,
Contact:13813902930 025-52714267
Address:20 Fengji Road, Yuhua Economic Development Zone, Nanjing, Jiangsu, P. R. China
Contact:+86-25-83719363
Address:106-7 Chunnan Rd, Chunxi Town, Gaochun, Nanjing, China
Weifang Jahwa Chemical Co.,Ltd
Contact:0086-536-8897731,8897730
Address:No.5166 East Dongfeng Street,Weifang,Shandong,China
Xi'an Unique Electronic and Chemical Co., Ltd.
Contact:+86-029-88238008
Address:1703# B BUILDING WEST ELECTRONIC ZONE, XI'AN, CHINA
Doi:10.1016/j.ica.2010.12.022
(2011)Doi:10.1081/NCN-100105903
(2001)Doi:10.1016/j.bmc.2011.01.032
(2011)Doi:10.1021/ja00176a063
(1990)Doi:10.1002/hlca.19900730218
(1990)Doi:10.1055/s-0029-1218715
(2010)
