Synthetic studies on gelsedine alkaloids-I: Stereoselective preparation of hypothetical biogenetic intermediates, D-Norsarpagine type compounds from ajmaline

DOI: 10.1016/S0040-4039(00)88787-0

Source and publish data:

Tetrahedron Letters p. 1287 - 1290 (1990)

Update date:2022-07-29

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Authors:

Takayama

Horigome

Aimi Aimi

Sakai Sakai

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Article abstract of DOI:10.1016/S0040-4039(00)88787-0

D-Norsarpagine type compound (4) and its C/D ring-opening derivative (22), which were corresponding to the hypothetical biogenetic intermediate for gelsedine (6), were prepared from ajmaline (3) via the deformylation (C₂₁) and the construction

Full text of DOI:10.1016/S0040-4039(00)88787-0

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