Tetrahedron Letters p. 3987 - 3990 (1990)
Update date:2022-09-26
Topics:
Kumarathasan, Rajkumar
Boudjouk, Philip
The rate of alcoholysis of 1,1-di-t-butylsiliranes is significantly accelerated in the presence of 10percent KF and still further enhanced by the addition of 1percent 18-crown-6.A pentacoordinate siliconate is proposed as the intermediate responsible for the observed rate increases.
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