A NEW SYNTHESIS OF ANGULARLY SUBSTITUTED BICYCLIC SYSTEMS VIA AN ANIONIC OXY-COPE REARRANGEMENT

DOI: 10.1016/S0040-4020(01)81524-6

Source and publish data:

Tetrahedron p. 3559 - 3568 (1990)

Update date:2022-08-05

Topics:

Authors:

Sathyamoorthi, G.

Thangaraj, K.

Srinivasan, P. C.

Swaminathan, S.

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Article abstract of DOI:10.1016/S0040-4020(01)81524-6

A general synthesis of trans bicyclic carbinols with an angular methyl substituent using the anionic oxy-Cope rearrangement is reported.The carbinols 13a, 13b, 14a and 15 furnish the bicyclic carbinols 16a, 16b, 17a, 17b and 18 when treated with potassium

Full text of DOI:10.1016/S0040-4020(01)81524-6

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