REMOTE ACYCLIC STEREOCONTROL; CHIRAL SYNTHESIS OF (+)-PEDAMIDE

DOI: 10.1016/0040-4020(84)80017-4

Source and publish data:

Tetrahedron p. 2337 - 2344 (1984)

Update date:2022-08-02

Topics:

Authors:

Matsumoto, Takeshi

Matsuda, Fuyuhiko

Hasegawa, Kazuo

Yanagiya, Mitsutoshi

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Article abstract of DOI:10.1016/0040-4020(84)80017-4

Synthesis of optically active pedamide (3), one of the tetrahydropyran moieties of the potent insect poison pederine (1), has been accomplished through a new, remote controlled asymmetric reduction of a ketone as key step.

Full text of DOI:10.1016/0040-4020(84)80017-4

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