Synthesis of 3''-Dehydro-4-O-methylbarminomycin II Having an Eight-membered Acetal-azomethine Ring

DOI: 10.1246/cl.1990.1431

Source and publish data:

Chemistry Letters p. 1431 - 1432 (1990)

Update date:2022-08-04

Topics:

Authors:

Ikeda, Daishiro

Ajito, Keiichi

Kondo, Shinichi

Takeuchi, Tomio

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Article abstract of DOI:10.1246/cl.1990.1431

Barminomycin I and II, an extremely potent antitumor anthracyclines, have a unique eight-membered azomethine or carbinolamine structure. (1''R,5''R)-3''-Dehydro-4-O-methylbarminomycin II was first synthesized through the hypothetical biogenetic intermedia

Full text of DOI:10.1246/cl.1990.1431

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