
Chemistry Letters p. 1147 - 1150 (1990)
Update date:2022-07-29
Topics:
Mukaiyama, Teruaki
Uchiro, Hiromi
Kobayashi, Shu
The asymmetric aldol reaction between both achiral silyl enol ethers of thioesters and aldehydes is efficiently catalyzed by the use of a new catalyst system consisted of tin(II) oxide, trimethylsilyl triflate and a chiral diamine, to give the corresponding adducts in high yields with high diastereo- and enantioselectivities.
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