Chiral titanium complex-catalyzed Diels-Alder reaction: A practical route to anthracycline intermediates

DOI: 10.1016/S0957-4166(00)86118-2

Source and publish data:

Tetrahedron Asymmetry p. 643 - 646 (1991)

Update date:2022-08-02

Topics:

Authors:

Mikami Mikami

Terada Terada

Motoyama

Nakai Nakai

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Article abstract of DOI:10.1016/S0957-4166(00)86118-2

Asymmetric Diels-Alder reactions of methacrolein and 1,4-naphthoquinone with 1,3-dienol derivatives catalyzed by the chiral binaphthol (BINOL)-derived titanium complex 1 are shown to provide the corresponding endo-adducts in high enantiomeric purity. The

Full text of DOI:10.1016/S0957-4166(00)86118-2

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