Tetrahedron Letters p. 5061 - 5064 (1990)
Update date:2022-07-29
Topics:
Tomioka
Watanabe
Kobayashi
Hirai
Phenylphosphonylcarbene generated in gas phase at high temperature produced 1,2-oxaphosphetane 1-oxides as a result of intramolecular C-H insertion into ester alkyl group, which underwent fragmentation leading to styrene derivatives and metaphosphate at higher temperature.
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