STEREOCONTROLLED SYNTHESIS OF HIGHLY FUNCTIONALIZED CYCLOHEXENES. A SHORT SYNTHESIS OF A CHORISMIC ACID PRECURSOR

DOI: 10.1016/S0040-4020(01)85582-4

Source and publish data:

Tetrahedron p. 4573 - 4586 (1990)

Update date:2022-09-26

Topics:

Authors:

Posner, Gary H.

Nelson, Todd D.

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Article abstract of DOI:10.1016/S0040-4020(01)85582-4

A convenient and mild thermal procedure has been developed for stereoselective 2+4-cycloadditions of electron-rich 1,2-dioxygenated olefins 7 to electron-deficient 3-sulfonyl-2-pyrone 6 allowing isolation of the structurally and stereochemically rich init

Full text of DOI:10.1016/S0040-4020(01)85582-4

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