Generation and Oligomerization of Bicyclooctyne and Properties of Tris(bicycloocteno)benzene Obtained from the Linear Trimer

DOI: 10.1021/jo00001a039

Source and publish data:

Journal of Organic Chemistry p. 195 - 203 (1991)

Update date:2022-09-26

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Authors:

Komatsu, Koichi

Aonuma, Shuji

Jinbu, Yasuhisa

Tsuji, Ryotaro

Hirosawa, Chitaru

Takeuchi, Ken'ichi

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Article abstract of DOI:10.1021/jo00001a039

Reaction of 2,3-dibromobicyclo<2.2.2>oct-2-ene (10) with n-butyllithium in THF at -78 deg C affords a series of oligomeric dibromides 11 (n = 2-5), which are composed of linearly bonded bicyclo<2.2.2>oct-2-ene units.A trapping experiment indicated that th

Full text of DOI:10.1021/jo00001a039

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