Tetrahedron Letters p. 3363 - 3366 (1990)
Update date:2022-08-02
Topics:
Jones, Raymond C. F.
Jones, Richard F.
A hexahydroindane precursor to the as-hydrindacene portion of ikarugamycin is prepared by a stereoselective Michael reaction-Diels-Alder reaction sequence; a second Michael reaction in the desalkyl series produces an indeno[4,5-c] furan isomer of the as-hydrindacene carbotricycle. A hexahydroindane precursor to the as-hydrindacene portion of ikarugamycin (1) is prepared by a stereoselective Michael reaction-Diels-Alder reaction sequence; a second Michael reaction in the desalkyl series produces an indeno[4,5-c]furan isomer of the as-hydrindacene carbotricycle.
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