Co-ordination Chemistry of Higher Oxidation States. Part 35. Synthetic, Spectroscopic, and Electrochemical Studies of some mer- and fac-/+ Systems (L= PR3, AsR3, SbR3, or pyridine; X= Cl or Br): Crystal Structure of fac-<Os(PEt2

DOI: 10.1039/DT9900002609

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2609 - 2616 (1990)

Update date:2022-08-04

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Authors:

Cipriano, Robert A.

Levason, William

Mould, Roy A. S.

Pletcher, Derek

Webster, Michael

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Article abstract of DOI:10.1039/DT9900002609

The complexes mer- (L= PMe3, PEt3, PEt2Ph, PEtPh2, or AsEt3; X= Cl or Br) are oxidised by HNO3-HBF4 to mer-BF4; fac- and merBF4 (py= pyridine) were obtained similarly, but attempts to oxidise fac- (L'= PR3 or AsR3) or

Full text of DOI:10.1039/DT9900002609

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