Palladium-catalyzed asymmetric alkylation via II-allyl intermediate: Acetamidomalonate ester as a nucleophile

DOI: 10.1016/S0040-4039(00)97803-1

Source and publish data:

Tetrahedron Letters p. 5049 - 5052 (1990)

Update date:2022-07-31

Topics:

Authors:

Yamaguchi

Shima Shima

Yamagishi

Hida Hida

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Article abstract of DOI:10.1016/S0040-4039(00)97803-1

Asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate with sodium salt of acetamidomalonate ester has been carried out in the presence of a palladium catalyst containing (S)-BINAP to give a chiral α-allyl-α-acetamidomalonate ester derivative of high optical purity (94 ± 1% ee).

Full text of DOI:10.1016/S0040-4039(00)97803-1

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Product name:2-Acetylamino-2-((E)-(S)-1,3-diphenyl-allyl)-malonic acid dimethyl ester

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