Palladium-catalyzed asymmetric alkylation via II-allyl intermediate: Acetamidomalonate ester as a nucleophile

DOI: 10.1016/S0040-4039(00)97803-1

Source and publish data:

Tetrahedron Letters p. 5049 - 5052 (1990)

Update date:2022-07-31

Topics:

Authors:

Yamaguchi

Shima Shima

Yamagishi

Hida Hida

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)97803-1

Asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate with sodium salt of acetamidomalonate ester has been carried out in the presence of a palladium catalyst containing (S)-BINAP to give a chiral α-allyl-α-acetamidomalonate ester derivative of high optical purity (94 ± 1% ee).

Full text of DOI:10.1016/S0040-4039(00)97803-1

Products guided by the article

Product name:2-Acetylamino-2-((E)-(S)-1,3-diphenyl-allyl)-malonic acid dimethyl ester

Cas No:131003-39-9

R&D Labs maybe for 131003-39-9

guide(suzhou) fine materials co. ltd

Contact:0512-80972173

Address:21st Building, No.369 Lushan Rd, New District Suzhou China 215129
Anhui New Star Pharmaceutical Development Co., Ltd

Contact:013956922763

Address:Floor 3, F9A, F Workshop, No.110 Kexue Road, High-Tech Development Zone, Hefei, Anhui ,China
Xi'an Costrong Pharmaceutical Co., Ltd.

Contact:029- 68576496

Address:Room 2004,Shuibao Building,No.190,South Erhuan Rd, Yanta District,Xi'an,Shaan Xi,China
Changzhou Sunlight Pharmaceutical Co., Ltd.

Contact:+86-519-83131668;83139028;83138042;83137041

Address:JiuliStreet, Benniu Town Changzhou City, Jiangsu Province
Shaanxi Sinuote Biotech Co.,Ltd

Contact:+86-29-68859685

Address:No 18,Taiyuan Road ,Xi'an city ,China

Relevant to this article

3,7-Disubstituted octahydro-1,5-diazocines. Their conversion into tetrahydro-1,5-diazocines and into ring-contracted products.

Doi:10.1021/jo01283a014
(1967)
REARRANGEMENT OF 1-ACETYLINDOXYL OXINE TO 1-ACETYL-2-CHLORO-3-IMINOINDOLINE HYDROCHLORIDE

Doi:10.1007/BF00487425
(1990)
Design, synthesis, biological evaluation, and Structure - Activity relationships of substituted phenyl 4-(2-oxoimidazolidin-1-yl)benzenesulfonates as new tubulin inhibitors mimicking combretastatin A-4

Doi:10.1021/jm200488a
(2011)
A new disubstituted polyacetylene bearing pyridine moieties: Convenient synthesis and sensitive chemosensor toward sulfide anion with high selectivity

Doi:10.1021/ma200777e
(2011)
Functionalization of mesoporous carbon with superbasic MgO nanoparticles for the efficient synthesis of sulfinamides

Doi:10.1002/chem.201002885
(2011)
Synthesis and evaluation of bidentate ligands designed to interact with PDZ domains

Doi:10.1016/j.bmc.2011.05.036
(2011)

Article Doi