Reaction of Bistrifluoromethylaminosulphenyl Chloride with Hydrocarbon Olefins and the Synthesis of Bistrifluoromethylaminosulphenylarenes

DOI: 10.1016/S0022-1139(00)85244-6

Source and publish data:

Journal of Fluorine Chemistry p. 91 - 96 (1982)

Update date:2022-08-02

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Authors:

Service, Colin F.

Tipping, Anthony E.

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Article abstract of DOI:10.1016/S0022-1139(00)85244-6

Reaction of bistrifluoromethylaminosulphenyl chloride with acyclic and alicyclic hydrocarbon olefins at -78 deg C in the dark affords 1:1 adducts of type in high yield.Treatment of diaryl disulphides with the N-bromo-amine (CF3)2NBr or of benzenesulphenyl chloride with the mercurial <(CF3)2N>2Hg provide convenient routes to bistrifluoromethylaminosulphenylarenes.

Full text of DOI:10.1016/S0022-1139(00)85244-6

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