Total synthesis of (±)-9-deoxygoniopypyrone. Application of the iodocyclofunctionalization reaction of α-allenic alcohol derivatives

DOI: 10.1139/v97-212

Source and publish data:

Canadian Journal of Chemistry p. 94 - 101 (1998)

Update date:2022-08-04

Topics:

Authors:

Friesen, Richard W.

Bissada, Suzanne

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Article abstract of DOI:10.1139/v97-212

The synthesis of (±)-9-deoxygoniopypyrone (1) from the α-allenic alcohol 5 is described. Iodocyclofunctionaliztion of the N-tosyl carbamate derivative of 5 using I₂ and Ag₂CO₃ provided, in a highly diastereoselective and r

Full text of DOI:10.1139/v97-212

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