Journal of Organic Chemistry p. 1434 - 1439 (1991)
Update date:2022-08-04
Topics:
Sonawane, Harikisan R.
Bellur, Nanjundiah S.
Ahuja, Jaimala R.
Kulkarni, Dilip G.
Treatment of α-diazo ketones 1a-d and 2a-d with catalytic amounts of rhodium(II) acetate led to selective carbene insertions into C-H bonds resulting in cyclopentane-annulated products in high yields.The highly selective insertion realized into the exo-methyl C-H bond of 1a has been utilized in the syntheses of (+)-albene (8) and (-)-β-santalene (11).
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