
Tetrahedron Asymmetry p. 251 - 264 (1990)
Update date:2022-08-05
Topics:
Annunziata, Rita
Cinquini, Mauro
Cozzi, Franco
Giaroni, Paola
Raimondi, Laura
The intramolecular cycloaddition to vinyl sulphur derivatives of a series of nitrones featuring an alkyl or alkoxy substituted α-stereocenter on the tether connecting dipol and dipolarophile occurs in a competely stereoselective fashion to give 3',3-anti configurated products.The synthetic potentialities of this reaction is illustrated by the synthesis of a precursor of (d)-biotin.
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(2011)Doi:10.1055/s-1990-27066
(1990)Doi:10.1021/jo200924y
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