Tetrahedron Letters p. 5147 - 5150 (1990)
Update date:2022-08-03
Topics:
Fournet, Guy
Balme, Genevieve
Van Hemelryck, Bruno
Gore, Jacques
Vinyl and aryl halides react with ε-acetylenic β-diesters, β-keto esters and βsulfonylesters in the presence of a Pd(o) catalyst leading in good yields to the title compounds. The acetylenic homolog containing an additional carbon leads in the same conditions to a cyclohexane, but this process then competes with the arylation of the terminal acetylenic carbon.
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Doi:10.1039/c8ob00583d
(2018)Doi:10.1039/c5cc02677f
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