Cumulenes as ligands IV. Rhodium and platinum complexes of tetraphenylhexapentaene. X-ray crystal structure of bis(triphenylphosphine)chloro(tetraphenylhexapentaene)rhodium

DOI: 10.1016/0022-328X(90)85279-8

Source and publish data:

Journal of Organometallic Chemistry p. 219 - 226 (1990)

Update date:2022-08-02

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Authors:

Song, Linsheng

Arif, Atta M.

Stang, Peter J.

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Article abstract of DOI:10.1016/0022-328X(90)85279-8

The interaction of tetraphenylhexapentaene with chlorotris(triphenylophosphine) rhodium produces a red complex in which rhodium is bound to the second C=C bond of the cumulene.In contrast, reaction of the same cumulene with (PPh3)2Pt⁰ generated

Full text of DOI:10.1016/0022-328X(90)85279-8

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