Efficient Trapping of Ketone Enolates with Acrylate and β-Sulfonylacrylate Thioesters, β-Sulfonyl-, β-sulfinyl- and β-Chloro-vinyl Ketones; Facile Preparation of a Hydrindanone, cis-Dimethyloctalone, and Unsaturated 1,5-Dicarbonyl Compounds

DOI: 10.1071/CH9901375

Source and publish data:

Australian Journal of Chemistry p. 1375 - 1389 (1990)

Update date:2022-07-30

Topics:

Authors:

Dancer, Robert J.

Haynes, Richard K.

Laughlin, Wendy A.

Vonwiller, Simone C.

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Article abstract of DOI:10.1071/CH9901375

Tandem conjugate addition-ring closure involving reaction of the lithium enolate arising from conjugate addition of lithiated (E)-but-2-enyldiphenylphosphine oxide to 2-methyl-cyclopent-2-enone with two moles of t-butylthioacrylate generates a hydrindanol

Full text of DOI:10.1071/CH9901375

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